In a bowl, combine all dry ingredients (flour, sugar and baking powder).
Melt the chocolate and butter together using a double boiler, or place a metal bowl over a pot of simmering water and add the chocolate/butter to the bowl to melt it, stirring occasionally.
Add the melted chocolate/butter mixture to the dry ingredients and mix together with a wooden spoon. Add the eggs and vanilla. Mix until well combined.
Lightly oil the cake pop maker cooking plates. Plug it in to preheat. Pour brownie batter into a piping bag.
With the piping bag, transfer the batter into the cake pop maker cavities, to just below the top of the cavity. (Alternatively, you can use a teaspoon to transfer the batter.)
Close the lid and bake for about 8 minutes, or until baked through. I like to use a narrow spatula with a heat glove on to remove them.
They will be hot inside, so let them cool and enjoy!
Notes
Store these bites in an airtight container to preserve freshness, and enjoy for up to 4 days!
If you don't want to make the full batch at once, you can freeze the brownie batter for later use.
You can also freeze the baked cake bites in a freezer bag for up to 3 months.
Instead of using a double boiler, you can melt the chocolate and butter in the microwave, in a microwave safe bowl, at 20 second intervals. Stir each time until fully melted.